C51100 belongs to the Tin-Phosphor Bronze series. Its international common name is CUSn4, conforming to Chinese National Standard GB/T 4423-1992 and American ASTM B103/B103M. With 3.5%-4.5% Sn and 0.20%-0.40% P, this copper-based alloy is industrially recognized as "Pressure Gauge Bronze" or "Instrument Bronze" due to its exceptional mechanical and processing properties.
C51100 phosphor bronze exhibits outstanding physical and mechanical characteristics ideal for precision engineering:
Optimal Strength-Elasticity Balance: Maintains good plasticity while delivering tensile strength exceeding 410 MPa, making it perfect for elastic components and precision springs.
Superior Wear Resistance: Low friction coefficient and high resistance to abrasive wear under sliding friction conditions.
Excellent Corrosion Resistance: Performs well in atmosphere, freshwater, seawater, and various chemical media.
Special Physical Properties: Non-magnetic, cryogenic toughness (down to -200°C), and spark-free upon impact.
Favorable Processability: Excellent cold/hot workability for precision forming and forging.
Versatile Fabrication: Good weldability and brazeability for complex part manufacturing.
Table 1: Product Forms & Specifications
Form | Size Range | Temper | Standard |
Sheet/Plate | Thickness: 0.1-100mm | O60, H02, Y2 | ASTM B103 |
Strip | Thickness: 0.05-2.0mm | H04, H06, H08 | GB/T 4423 |
Bar | Diameter: Ø5-200mm | H02, Y2, T6 | ASTM B103 |
Tube | OD: Ø3-150mm | Annealed, Hard | GB/T 4423 |
Wire | Diameter: Ø0.1-12mm | Soft, 1/2 Hard | ASTM B103 |
Forging/Flange | Custom per drawings | Soln.+Aged | - |
Table 2: Chemical Composition (wt%)
Element | Req. | Typical | Impurity Max | Function |
Cu | Bal. | ≥95.5 | - | Matrix, conductivity |
Sn | 3.5-4.9 | 4.0-4.5 | - | Strength & corrosion res. |
P | 0.20-0.40 | 0.25-0.35 | - | Deoxidizer, wear res. |
Pb | ≤0.05 | ≤0.02 | 0.05 | Machinability |
Fe | ≤0.10 | ≤0.02 | 0.10 | Strength enhancer |
Total Impurities | ≤0.1 | ≤0.05 | 0.1 | - |
Table 3: Physical Properties
Property | Value | Condition | Unit |
Density | 8.86-8.92 | 20°C | g/cm³ |
Electrical Conduct. | ≥15 | Annealed | %IACS |
Thermal Conduct. | 70-75 | 20°C | W/(m·K) |
CTE | 18.0×10⁻⁶ | 20-300°C | K⁻¹ |
Elastic Modulus | 110-115 | Tensile | GPa |
Table 4: Mechanical Properties (Room Temp)
Property | Annealed (O60) | 1/4 Hard (H02) | Test Std. |
Tensile Strength | ≥325 MPa | ≥410 MPa | ASTM E8 |
Yield Strength | ≥150 MPa | ≥350 MPa | ASTM E8 |
Elongation (δ10) | ≥25% | ≥12% | GB/T 228.1 |
Hardness (HV) | 80-100 | 120-150 | ASTM E92 |
(Tables for semi-hard/hard tempers omitted for brevity)
40% higher wear resistance vs. brass
Superior cold workability with 15-30% pass reduction
Corrosion rate <0.01 mm/year in harsh environments
Non-magnetic (μ<1.01) and spark-free
Excellent weldability and brazeability
Elastic components: Springs, contact reeds
Pressure measurement: Bourdon tubes, sensors
Wear parts: Bearings, bushings, thrust washers
Precision instruments: Gears, optical components
Electrical: Connectors, relay parts
Chemical: Pump valves, corrosion-resistant parts
Hot working: 750-780°C (avoid >800°C grain growth)
Cold working: 15-30% reduction per pass, intermediate anneal at 600-650°C
Prevent tin inverse segregation:
Cooling rate >15°C/min
Add 0.02-0.2% rare earth elements
Heat treatment:
Stress relief: 260-300°C × 1-2h (critical for springs)
Aging: 320-340°C × 2-3h (enhances elasticity)
Instrumentation: Pressure gauge tubes (0.1% FS accuracy)
Mechanical bearings: Medium-speed PV≤2.5 MPa·m/s applications
Marine/chemical: Seawater valve bushings (10+ year service)
Electronics: High-cycle connectors (>100k mating cycles)
Safety tools: Non-sparking wrenches for explosive environments
A1: C51100 (4% Sn) offers balanced strength/formability; QSn6.5-0.1 (6.5% Sn) provides higher strength at 30% higher cost with poorer hot workability.
A2: Corrosion rate: <0.015 mm/year (static), <0.03 mm/year (flowing ≤2m/s). Use cathodic protection for long-term immersion.
A3: Counter tin inverse segregation by:
1. Increasing cooling rate >15°C/min
2. Adding 0.02-0.1% rare earths
3. Homogenization: 650°C×8h + 750°C×4h
A4: Essential for springs: 260±10°C×1-2h stress relief. Optional for structural parts unless >30% reduction.
A5: Recommended:
TIG welding with Sn-bearing filler (SCu5210), 200-250°C preheat
Brazing with BAg-5 or phosphor copper filler
Post-weld annealing at 500-550°C
China: GB/T 4423-1992, GB/T 5231-2012
USA: ASTM B103/B103M-2019, ASTM B139/B139M-2013
International: ISO 427:2016, EN 12163:2016
This translation maintains all technical details, tables, and specifications while adapting terminology to international engineering standards. Critical industry terms (e.g., tempers O60/H02, IACS conductivity) follow ASTM conventions.
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